A Classic

Kodak Microdol-X

Kodak's ultra-fine-grain methol developer is very similar to Perceptol, a product proven over decades by millions of photography enthusiasts.

About the Developer

Microdol-X was developed by Kodak and is very similar to Ilford’s Perceptol—a tried-and-true formula. It is also a variant of the popular D-25 developer: a metol-based, alkali-free developer. The only noticeable difference from Perceptol is that instead of sodium tripolyphosphate, it uses trisubstituted sodium citrate, which also creates a mild buffered environment. As with Perceptol, the sodium chloride must be chemically pure: ordinary table salt, even “Extra” grade, contains impurities of magnesium, calcium, and sulfate salts that are harmful to the film emulsion. Potassium chloride can be used in an equimolar amount instead of sodium chloride.

Character

A Kodak ultra-fine-grain metol developer, very similar to Perceptol and D-25 in composition and results: the same metol without active alkali, the same trade-off of “smooth grain in exchange for sensitivity.”

Best films

Officially tested with Kodak Tri-X 400 (see table); based on its composition and characteristics, it is also suitable for medium-speed films such as Ilford FP4+ or Fomapan 100, where grain fineness is more important than speed.

How to Prepare and Use

  1. 1Pour about 750 ml of warm water (~45°C) into a 1-liter container and dissolve a small amount of sodium sulfite (about 10 g) in it.
  2. 2After the sulfite has dissolved, add the metol and dissolve it completely.
  3. 3Add the remaining sodium sulfite, followed by the trisubstituted sodium citrate and sodium chloride—add each subsequent substance only after the previous one has completely dissolved.
  4. 4Let the developer cool to room temperature, then bring the volume of the solution up to 1 liter.
  5. 5If necessary, filter the prepared developer.

Film development times (official Kodak data)

FilmBreedingTime @ 20°C
Kodak Tri-X 400 (ISO 400)stock (undiluted)9 min 15 sec
Kodak Tri-X 400 (ISO 400)1:317 min

Time — starting point at 20°C/68°F, small tank, agitation every 30 seconds, according to the official Kodak Tri-X 320/400 development chart (publication F-4017). For other films (FP4+, Fomapan) from Kodak and Ilford, no separate tables using Microdol-X have been published—use these values only as a guide and verify them with a test strip.

Pros

  • One of the most tried-and-true ultra-fine-grain recipes in the history of photography
  • Kodak has officially tested it specifically with Tri-X 400—there are exact exposure times
  • Smoother and more predictable than many similar products

Cons

  • A noticeable loss of sensitivity, just like with Perceptol
  • Requires chemically pure reagents (sodium chloride, citrate)
  • Not suitable for push processes

Recipe for 1 liter

Metol
5.0 g
Metol
Sodium sulfite (anhydrous)
100.0 g
Sodium sulfite (anhydrous)
Sodium chloride
30.0 g
Sodium chloride
Trisubstituted sodium citrate
2.0 g
Trisubstituted sodium citrate

Dissolve the following substances in strict sequence in ~750 mL of warm water (~45°C): a portion of sodium sulfite → methanol → the remaining sulfite → trisodium citrate → sodium chloride. Add each substance only after the previous one has completely dissolved. Cool and make up to 1 L.

Chemical structures: PubChem (public domain)